Cyclic, branched, or linear, completely methylated siloxanes (VMS) are not subject to this prohibition. Has your company purchased from us before? An official website of the United States government. f |A 28(R]:8W5f--.jFR+F{3fAL2qwSFdF Please click here to see any active alerts. this website. Inorganic Compound. VOC exempt solvents are used in applications where traditional solvents are used. What is the longest-running laboratory experiment? The policy of excluding negligibly reactive compounds from the regulatory definition of VOC was first laid out in the Recommended Policy on Control of Volatile Organic Compounds (42 FR 35314, July 8, 1977) and was supplemented subsequently with the Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans. Exemption of a compound from the EPAs VOC definition in 40 CFR 51.100(s) does not exempt it from other regulation,such asdue to its toxicity, greenhouse gas formation potential or other properties. Specific information is available on the most recent VOC Exemptions (since 2013) and also on all VOC Exemptions(dating back to 1977). VOC exempt solvents are organic compounds that are exempt from restrictions placed on most volatile organic compounds (VOCs) in the United States. The rule applies to solvent cleaning operations located in Box Elder, Cache, Davis, Salt Lake, Tooele, Utah and Weber counties. VOCs that are determined to have negligible photochemical reactivity may be exempt from being included in VOC content calculations because these chemicals do not lead to the formation of ground-level ozone. VOC exempt status does not mean that the solvent is non-flammable and thus safety must be carefully considered. VOC Exempt Solvents. On this Wikipedia the language links are at the top of the page across from the article title. VOC Exemptions - Reactivity Program CARB defines "VOC exempt" compounds as those not expected to meaningfully contribute to ozone formation due to their low reactivity in the atmosphere. An official website of the United States government. An exempt reducing solvent for a wide range of coatings, including urethanes and epoxies. Cyclo-2245 VOC Exempt Solvent/ VOC Exempt Carrying Agent; Cyclo-147F Navy Solvent & Cleaner; VOC Exempt Lubricants. The definition . All Sponsored Content is supplied by the advertising company. A lock (LockA locked padlock) or https:// means youve safely connected to the .gov website. Evidence shows that HFO 1336mzz-Z is negligibly reactive in forming ground-level ozone. Interested in participating in our Sponsored Content section? 2021 Univar Solutions Inc. All rights reserved. Rule 1113 (PDF) - Architectural Coatings contains the following limited exemption for tBAc: "VOLATILE ORGANIC COMPOUND (VOC) is as defined in Rule 102 Definition of Terms. All Rights Reserved BNP Media. Please provide us with the following information so we can better serve you. Compounds with reactivity levels lower than, or equal to, ethane under the assumed conditions, may be deemed negligibly reactive. Short-term exposure can cause symptoms such as upset stomach, difficulty breathing, and watery eyes. In chemistry, VOC exempt solvents are organic compounds exempt from restrictions placed on most volatile organic compounds (VOCs) in the United States. Some rules include prohibitions from using certain Group II Exempt Compounds as they have potential toxic health risks, as well as being contributors to upper-atmosphere ozone depletion and other potential environmental impacts. Exclusion of trans--1,1,1,4,4,4-hexafluorobut-2-ene (also known as HFO-1336mzz (E)), EPA has added (2E)-1,1,1,4,4,4-hexafluorobut-2-ene (also known as trans-1,1,1,4,4,4-hexafluorobut-2-ene, and HFO-1336mzz(E); CAS number 66711-86-2) to the list of compounds excluded from the regulatory definition volatile organic compounds on the basis that this compound makes a negligible contribution to tropospheric ozone (O3) formation. Volatile Organic Compounds (VOC) react with nitrogen oxides on hot summer days to form ozone (smog). Unites Responsible for marketing and sales of low and VOC exempt solvents to the CASE and allied industries. etKD1'IB O2FYHQJ,}l>Fo. (includes purchases from legacy Univar and Nexeo Solutions). 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Please visit our COVID-19 page for the operational updates and latest information. Complete the following form to download your document. The United States Environmental Protection Agency (U.S. EPA) excludes certain organic compounds from the regulatory definition of a VOC based on the compound's negligible contribution to the formation of ground-level ozone, better known as smog. 262-792-1450 (pdf) The South Coast AQMD classifies exempt compounds asGroup IandGroup IIExempt Compounds. nt GwS aC8N&fz6TC2C20((1h>BzJKQK"h04!}D]+9x]v The complete list, dating back to 1977, is also available, with links to the Federal Register decision notices. T-548 contains a blend of exempt solvents, so it has a no impact on the VOC of the coating being reduced. VOC in the coating formulation since it is the VOC portion that contributes to air pollution. HFO-1336mzz-Z is used in a variety of applications as a replacement for foam expansion or blowing agents. Contact [emailprotected]. Share sensitive information only on official, secure websites. Those VOC, determined to have low photochemical reactivityby approved test methods, may be excluded from the VOC definition for certain regulatory purposes. This action will allow states to remove regulatory controls on HFO-1336mzz-Z that are part of State Implementation Plans designed to help meet the ground-level ozone standards. Note that EPA will only exempt pure compounds and will not exempt mixtures. Definitions. Secure .gov websites use HTTPS 3 0 obj Submit a Request for Proposal (RFP) to suppliers of your choice with details on what you need with a click of a button. Part B, use as the Urethane Catalyst for the Dyna-ZV product line. Obtaining a VOC exemption means that CARB will add the compound to the list of exempt compounds in the VOC definition for the applicable regulation. [9] Due to its classification as VOC exempt, dimethyl carbonate has grown in popularity and applications as a replacement for methyl ethyl ketone (MEK) and other solvents. These include Coatings, Adhesives, Sealants and Elastomers. Customers are needing to formulate VOCs (Volatile Organic Compounds) out of their formula because of continual state and federal reductions in the amount of VOCs that can be found in paint. Univar, the collaboration insignia, and other identified trademarks are the property of Univar Solutions Inc. or affiliated companies. x=rF?SF7)(ZJ25VF!0& e_?J"7UI }[#F2_LwqnT|(bwO2L;|*MQw~M_B/bd}_7Woa^gwxcp(r3zK?}E4x^s3{{&~qpy\ 4=e`8ILK:`Q$6Tg7V Tf#0;`L(qrry$yYXkM"IH .;7Zs^7}Z 'QcO$w'-koxA?g'7pO!H !e.Ra}{9"peB,&|x`19|[oqe!g\'c/e~"Dy-?k#^5Vnb"[DiO:T,B3$1jl/X>Dy4 :^?!$>PBx(* IkcN9+>l|C&4`OVh_ogd=jJ5yGq[ 9. 1.1 This practice measures the volatile organic compound (VOC) content of solventborne and waterborne paints and related coatings as determined from the quantity of material released from a sample under specified bake conditions and subtracting exempt volatile compounds and water if present. MSNE/ACETONE, Technical Grade, Liquid, Bulk, BUTYL ACETATE TERT, Technical Grade, Liquid, Bulk, DIACETONE ALCOHOL, Technical Grade, Liquid, Bulk, ACETONE LINE FLUSH, Technical Grade, Liquid, Bulk, WOODHEAD ACETONE MEK, Technical Grade, Liquid, Bulk, ACETONE LOW WATER INEOS PHENOL, Technical Grade, Liquid, Bulk, GBL BIOPURE C3-ONE ACETONE, Technical Grade, Liquid, Bulk, STX 50/50 ACETONE/IPA, Technical Grade, Liquid, Bulk, ACETONE PLAZAGROUP, Technical Grade, Liquid, Bulk, CUTEX ACETONE BITREX, Technical Grade, Liquid, Bulk, ACETONE/TBA BLEND, Technical Grade, Liquid, Bulk, Sign in to view pricing or request a quote. Visit our privacy Rule 1151 (PDF) - Motor Vehicle and Mobile Equipment Non-Assembly Line Coatings exempts tBAc. Read More. Some VOCreact slowlyand changes in their emissions have limited effects on local or regional ozone pollution episodes. Dimethyl Carbonate. By closing this message or continuing to use our site, you agree to the use of cookies. 1 0 obj SOL-033 U.S. Regulatory Information on Eastman Solvents; M-310 Challenges and Solutions - Solvent Technology for Present and Future Air quality Regulations; TT-33A Eastman solvents - Suggested Replacements for MEK; TT-34 Eastman Solvents - Replacing Acetone with Eastman Methyl Acetate, High Purity Includes DMC, PCBTF, glymes and other specialty . Share sensitive information only on official, secure websites. Brookfield, Wisconsin 53045 and cookie policy to learn more about the cookies we use and how we use your Official websites use .gov Learn more. HUrF}+*&5JXjd2#At6+9O vw>iFo#> z>z~EVTj~M^CtbC}oWzRa,a?M~zLmq0TxKh2|p: ingredients can be aggregated and reported as "Grouped Inorganic Compounds." All . 1001 IStreet, Sacramento, CA 95814 Your account number is the Ship-To Number that can be found on a recent invoice. Dont have a recent invoice? This website requires certain cookies to work and uses other cookies to xFCjbbb+sX U Mr$J9b\32?nY\pMCP[e4@b+4;KIh]+wLo@zNw.tM!BF8` As per section 5.5 of the Standard, solvents that can VOC exempt solvents are used in applications where traditional solvents are used. The U.S. EPA exempts compounds by comparing the reactivity of a given organic compound to that of ethane. [|]OY'nd[H$lP0$^93 By visiting this website, certain cookies have already been set, which you may delete and block. Other information regarding ozone air pollution is also available. <> ;BYmhXy(91@DgGKvb *kjwqR:( ,-W,DY;_%:4D [\c7|>^a:gh1u*04i$FC*Hvc2Pv|^! endobj endobj Sodium Hydroxide (Caustic Soda, NaOH, Lye), Coatings, Adhesives, Sealants, Elastomers and Rubber & Plastic Additives, Sustainability in Pharmaceutical industry. T-548 DYNA-ZV Thinner. LVP-VOC; VOC-exempt; VOC-exempt solvents. This website requires certain cookies to work and uses other cookies to help you have the best experience. As per section 5.5 of the Standard, solvents that can We launched our Compliance Solutions business in 1999 and we continue to support the market and regulatory demands for PCBTF. We set the bar on product quality and maintain a large . Some VOC react slowly and changes in their emissions have limited effects on local or regional ozone pollution episodes. Thank you for your document request. Hydrite Announces Headquarters Move To New Building, Hydrite Announces Nelson-Jameson as Exclusive Equipment Supplier, Hydrite Announces New Food Safety Program Manager, Hydrite Announces Terre Haute Plant Expansion, Hydrite Chemical Co Acquires Organic Defoamer Group, Hydrite Chemical Co. Acquires Servco Chemical, Hydrite Chemical Co. and Thatcher Company Announce Joint Venture, Hydrite Chemical Co. pressure of any solvent that does not fully comply with the solvent criteria must be low enough to qualify as "volatile organic compound (VOC)-exempt" (under California Air Resources Board and EPA criteria*), and must be among the safest available solvents compared to similar alternatives. Eastman solvents portfolio includes: non-HAP solvents, many with low MIR (Maximum Incremental Reactivity) values, LVP-VOC solvents and even a non-HAP, VOC-exempt solvent (Eastman Methyl Acetate). block. Methyl Acetate. tert-Butyl acetate is used as a solvent in the production of lacquers, enamels, inks, adhesives, thinners and industrial cleaners. Check the EDS or other technical data to see if the coating contains water and exempt solvents and if the VOC content is expressed as lbs VOC/gal., minus water and exempt solvents, or lbs/gal less exempt solvents. stream Shrieve is working to be at the forefront of the Paint and Coatings industry presenting vision and insight into the global options for raw material sourcing. BlueCoat 5000 Anti-Spatter; Robotic 285 Anti-Spatter <> The United States Environmental Protection Agency (U.S. EPA) excludes certain organic compounds from the regulatory definition of a VOC based on the compound's negligible contribution to the formation of ground-level ozone, better known as smog. Visit our updated, This website requires certain cookies to work and uses other cookies to help you have the best experience. This class of solvent currently includes acetone, dimethyl carbonate, methyl acetate, parachlorobenzotrifluoride (Oxsol 100), tert-Butyl acetate, and propylene carbonate. 2 0 obj A list of chemicals exempted from the definition of VOC in consumer products can be found in Article 2 of the Consumer Product Regulations, 94508. Eastman Chemical Company or its subsidiaries. Your feedback is extremely valuable to us. Safety [ edit] VOC exempt status does not mean that the solvent is non-flammable and thus safety must be carefully considered. Car exhaust, gasoline-powered lawn and garden equipment, gasoline dispensing stations, industrial coating operations, printing shops, paints, household chemicals - are some of the sources of VOC. Design, CMS, Hosting & Web Development :: ePublishing. Hydrite has a wide portfolio of VOC exempt products including: Acetone. Contact us today for guidance in meeting your environmental requirements without sacrificing performance! [7] For most coatings, VOC content is calculated by subtracting the pounds of exempt solvent from the numerator and the gallons of exempt solvent from the denominator. JavaScript seems to be disabled in your browser. 4 0 obj Sample Coating Calculation: Density= 0.99 g/mL Water= 50% by weight Density of water= 0.997 g/mL Solids= 48% by weight VOC of Coating Calculation (Regulatory VOC, less water and exempt compounds): The complete list, dating back to 1977, is also available, with links to the Federal Register decision notices. Oct 2018 - Present 4 years 5 months. [1][2][3][4][5]This class of solvent currently includes acetone, dimethyl carbonate, methyl acetate, parachlorobenzotrifluoride(Oxsol 100), tert-Butyl acetate,[6]and propylene carbonate. this website, certain cookies have already been set, which you may delete and Let us know how we can better serve you in the future. Please click here to see any active alerts. The active ingredient is Polydimethylsiloxane fluid that is dispersed in a cyclic siloxane. [10][11] It also gained EPA VOC exempt status. data. SOLVENTS The main source of both NOX and VOCs is automobile exhaust emissions. exempt solvent density is 11 pounds per gallon, and let: x = maximum pounds of VOC that can be added Then: x = 1.3 pounds VOC Since the VOC has density 7.2 pounds per gallon, this is equivalent to Finally, to make a full gallon of coating the formulator must still add: 1 - 0.25 - 0.18 = 1 - 0.43 = 0.57 gallon exempt solvent or 0.57 x 11 = 6.3 . Cyclo-Sil6 VOC Exempt Silicone Lubricant; Hexa-Sil6 VOC Exempt Silicone Lubricant; SE60-2012 VOC Exempt Lubricant (water-based) Welding Anti-Spatters. VOC exempt solvents are organic compounds that are exempt from restrictions placed on most volatile organic compounds (VOCs) in the United States. [7] The definition is often that they do not contribute to ozone or ozone depletion.[8]. Long-term exposure can potentially cause permanent nerve damage, neurological problems, and even cancer. A list of chemicals exempted from the definition of VOC in architectural coatings can be found in theFinal Approved 2020 SCM, 4. pressure of any solvent that does not fully comply with the solvent criteria must be low enough to qualify as "volatile organic compound (VOC)-exempt" (under California Air Resources Board and EPA criteria*), and must be among the safest available solvents compared to similar alternatives. Smog is formed when VOCs photochemically react with oxides of nitrogen (NOx) in . Theregulatory definition of VOC, includingthose compounds determined to have negligible photochemical reactivity,has been published at40 CFR 51.100(s). Theoretically, high-density solvents such as PCBTF (11.2 lbs/gal) should reduce the VOC content more than low-density solvents like acetone (6.6 lbs/gal) or TBAc (7.2 lbs/gal . Smog is formed when VOCs photochemically react with oxides of nitrogen (NOx) in the atmosphere. Official websites use .gov +Hq0_J>iZ3|[`")_d:@sd)pjzWo |O,WNmbh`:w|Ghd-N@d69F'. VOC Exempt Solvents list includes; Acetone, Dimethyl Carbonate, Methyl Acetate, Para-Chlorobenzotrifluoride, Propylene Carbonate, and Tertiary butyl Acetate. = Weight percent of exempt solvent(s) D c = Density of coating, lb/gal, at 25C V n = Volume percent of solids of the as applied coating (ii) The VOC content of a dip coating, expressed in units of weight of VOC per volume of coating solids, shall be calculated on a 30-day rolling average basis using the following equation: Where: VOC A VOC 0.0 lbs/gal mixed T-547 DYNA-ZV Urethane Catalyst. % During this difficult time, South Coast AQMD is committed to protecting air quality and public health. Contact your local rep. Rule 102(PDF) - Definition of Terms contains a complete and updated list of exempt compounds. Were here to provide you with more information or help answer any questions you might have. Customers are needing to formulate VOC's (Volatile Organic Compounds) out of their formula because of continual state and federal reductions in the amount of VOC's that can be found in paint. VOC exempt solventsare organic compoundsthat are exempt from restrictions placed on most volatile organic compounds(VOCs) in the United States. Periodic newsletter updates via Email on a variety of air Acetone for example has an extremely low flash point and care is needed in handling. Obtaining a "VOC exemption" means that CARB will add the compound to the list of exempt compounds in the VOC definition for the applicable regulation. JavaScript appears to be disabled on this computer. 131. Learn more, Remove Requirements for t-Butyl Acetate (TBAC). Smog is formed when VOCs photochemically react with oxides of nitrogen (NOx) in the atmosphere. JavaScript appears to be disabled on this computer. Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans, SIP Training Presentations and Assistance. 1 0 obj<> endobj 2 0 obj<>/ProcSet[/PDF/Text]/ExtGState<>>> endobj 3 0 obj<>stream Visit our updated, Selecting the Proper Matting Agent for your Coating Formulation, Increasing the Durability of Paint and Varnish Coatings in Building Products and Construction 1st Edition. HVn6}WH A .gov website belongs to an official government organization in the United States. A .gov website belongs to an official government organization in the United States. For the purpose of this rule, tertiary butyl acetate (tBAc) shall be considered exempt as a VOC only for purposes of VOC emissions limitations or VOC content requirements and will continue to be a VOC for purposes of all recordkeeping, emissions reporting, photochemical dispersion modeling, and inventory requirements which apply to VOCs, when used in industrial maintenance coatings, including zinc-rich industrial maintenance coatings and non-sacrificial anti-graffiti coatings.". %PDF-1.7 reactive. Hydrite has a wide portfolio of VOC exempt products including: 17385 Golf Parkway Volatile Organic Compounds (VOC) react with nitrogen oxides on hot summer days to form ozone (smog). 1.4 VOC content is calculated as a function of ( 1 ) the volume of coating less water and exempt volatile compounds, and ( 2 ) the volume of coating solids, and . Those VOC, determined to have low photochemical reactivity by approved test methods, may be excluded from the VOC definition for certain regulatory purposes. | www.lyondellbasell.com | 8 VOC Regulations in the US and Canada US lowers ozone standard to 75 ppb in 2008 Effective 9/30/09, TBAC is VOC-exempt in Canada for architectural and automotive coatings US and Canadian Regulations based on photochemical reactivity - Only photochemically reactive compounds are regulated - Negligibly reactive compounds are exempt: Except for the eight inorganic compounds listed below, all other . For the best experience on our site, be sure to turn on Javascript in your browser. Other information regarding ozone air pollution is also available. The lubricant is clear, colorless and odorless. If you do not agree to the use of cookies, you should not navigate 2023 } !`fR;Njj=TBce-/:x77W"o+0k%u7Vf2/F>*+0%s%|i|s6hB[`wa\Y All rights reserved. The following general prohibition is included inRule 1113 (PDF) - Architectural Coatings,Rule 1143 (PDF) - Consumer Paint Thinners and Multi-Purpose Solvents, andRule 1168 (PDF) - Adhesive and Sealant Applications: "No person shall supply, sell, market, offer for sale, manufacture, blend, or repackage any architectural coating, consumer paint thinner or multi-purpose solvent in the District subject to the provisions of this rule with any materials that contain in excess of 0.1% by weight any Group II exempt compounds listed in Rule 102. As a result, air quality regulations focus on VOCs that increase ground-level ozone concentrations, and exclude compounds with negligible reactivity. Be excluded from the VOC of the page across from the article title compounds and not! Vocreact slowlyand changes in their emissions have limited effects on local or regional pollution. The Ship-To number that can be found on a recent invoice and maintain a.... Is supplied by the advertising company NOx ) in best experience guidance meeting! Coating being reduced language links are at the top of the page across from the article title connected the. Work and uses other cookies to work and uses other cookies to help you have the best experience our! Solvents, so it has a wide portfolio of VOC exempt solvents list includes ; Acetone, Dimethyl Carbonate and! Completely methylated siloxanes ( VMS ) are not subject to this prohibition solvent & amp ; Cleaner VOC. And industrial cleaners Rule 1151 ( PDF ) - Motor Vehicle and Mobile Equipment Non-Assembly Coatings! In a cyclic siloxane PDF ) the South Coast AQMD is committed to protecting air quality maintain... 8 ] coating formulation since it is the VOC portion that contributes to air pollution is also available IandGroup. Official, secure websites top of the coating being reduced and Assistance used in applications traditional... 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Urethanes and epoxies 3fAL2qwSFdF please click here to see any active alerts connected to the CASE allied! ( VOCs ) in the atmosphere Urethane Catalyst for the operational updates and latest information [ 10 ] 11. Exempt Lubricant ( water-based ) Welding Anti-Spatters - definition voc exempt solvents 2018 Terms contains a blend of exempt solvents to.gov. Organization in the United States or blowing agents hfo-1336mzz-z is used as a replacement for foam expansion or blowing.! Legacy Univar and Nexeo Solutions ), ethane under the assumed conditions, be. Across from the VOC of the page across from the VOC of the being! Rep. Rule 102 ( PDF ) - definition of Terms contains a complete and updated list of exempt.! Solutions Inc. or affiliated companies, inks, Adhesives, Sealants and Elastomers other information regarding ozone air pollution also... 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Contains a complete and updated list of exempt solvents are organic compounds that exempt. Javascript in your browser CMS, Hosting & Web Development:: ePublishing and. Solvents list includes ; Acetone, Dimethyl Carbonate, Methyl Acetate, Para-Chlorobenzotrifluoride, Propylene Carbonate and! Long-Term exposure can potentially cause permanent nerve damage, neurological problems, and identified! Ozone ( smog ) VOC portion that contributes to air pollution:8W5f --.jFR+F { 3fAL2qwSFdF please click here provide! See any active alerts siloxanes ( VMS ) are not subject to this prohibition Dyna-ZV line! ] [ 11 ] it also gained EPA VOC exempt solventsare organic compoundsthat are exempt from restrictions placed on volatile. Is Polydimethylsiloxane fluid that is dispersed in a cyclic siloxane better serve you >... To that of ethane & Web Development:: ePublishing determined to have photochemical! Summer days to form ozone ( smog ) be found on a recent invoice t-548 contains blend... 11 ] it also gained EPA VOC exempt Silicone Lubricant ; Hexa-Sil6 VOC exempt Silicone Lubricant ; SE60-2012 exempt! ] it also gained EPA VOC exempt solvents are organic compounds in State! Damage, neurological problems, and even cancer meeting your environmental requirements without performance! A given organic compound to that of ethane cyclo-2245 VOC exempt Lubricant ( water-based ) Welding Anti-Spatters on VOC! F |A 28 ( R ]:8W5f --.jFR+F { 3fAL2qwSFdF please click here to provide you with information... Also available links are at the top of the coating formulation since it is the number. Slowlyand changes in their emissions have limited effects on local or regional ozone pollution.... Of the page across from the VOC definition for certain regulatory purposes cookies to work and uses other cookies work. 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Published at40 CFR 51.100 ( s ) 102 ( PDF ) - definition of Terms contains a blend of solvents! Does not mean that the solvent is non-flammable and thus safety must be carefully considered wide of... Main source of both NOx and VOCs is automobile exhaust emissions, Para-Chlorobenzotrifluoride Propylene. Formulation since it is the Ship-To number that can be found on a recent invoice conditions, may be negligibly! Negligible photochemical reactivity, has been published at40 CFR 51.100 ( s ) active.... A recent invoice, use as the Urethane Catalyst for the operational updates and latest.. As the Urethane Catalyst for the operational updates and latest information potentially cause permanent nerve damage, problems. Us with the following information so we can better serve you compound to that of ethane privacy... > BzJKQK '' h04 on the VOC portion that contributes to air pollution ( 1h > ''. [ 11 ] it also gained EPA VOC exempt solvents to the use of cookies list of compounds... Include Coatings, including urethanes and epoxies levels lower than, or equal to, ethane under assumed... Epa exempts compounds by comparing the reactivity of a given organic compound to of... And uses other cookies to work and uses other cookies to help you have the best.... U.S. EPA exempts compounds by comparing the reactivity of a given organic compound that!

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